An infinite water chain passes through an array of Zn(II) metallocycles built with a podand bearing terminal carboxylates

被引：98

作者：

Neogi, S ^{[1
]}

Bharadwaj, PK ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 04期

关键词：

D O I：

10.1021/ic048489a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A podand bearing three carboxylic acid groups was synthesized by condensation of tris(2-chloroethyl)amine with 4-hydroxyethyl-benzoate followed by hydrolysis of the ester group. An aqueous solution of Zn(NO3)(2).6H(2)O reacts with the tetraethylammonium salt of the podand at room temperature, to form a porous coordination polymeric structure with infinite interlinked chains of Zn(II) metallocycles. An infinite water chain passes through the metallocycles like a thread. The compound was characterized by X-ray crystallography, X-ray powder diffraction, TGA, IR spectroscopy, and elemental analysis.

引用

页码：816 / 818

页数：3

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