Structures and solid-state dynamics of one-dimensional water chains stabilized by imidazole channels

被引：176

作者：

Cheruzel, LE ^{[1
]}

Pometun, MS ^{[1
]}

Cecil, MR ^{[1
]}

Mashuta, MS ^{[1
]}

Wittebort, RJ ^{[1
]}

Buchanan, RM ^{[1
]}

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 44期

关键词：

calorimetry; NMR spectroscopy; proton transport; solid-state structures;

D O I：

10.1002/anie.200352157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton wires: One-dimensional water chains play an important role in proton permeation through transmembrane proteins. The X-ray crystal structures as well as solid-state 2H and 17O NMR and calorimetry studies of two imidazole hydrates that stabilize infinite one-dimensional water chains are reported (see picture; N blue, O red, H white). The 2H NMR spectroscopic studies suggest that water molecules in both compounds undergo different reorientational dynamics.

引用

页码：5452 / 5455

页数：4

共 47 条

[1] THE GROTTHUSS MECHANISM [J].