Spatial Fourier-transform analysis of the morphology of bulk heterojunction materials used in "plastic" solar cells

被引:126
作者
Ma, Wanli [1 ]
Yang, Cuiying [1 ]
Heeger, Alan J. [1 ]
机构
[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
关键词
D O I
10.1002/adma.200601933
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Spatial Fourier transforms and power spectral density were used to analyze digital TEM images of bulk heterojunction material based on poly(3-hexylthiophene) as donor and a soluble fullerene (PCBM) as acceptor. Optimized high-temperature annealing leads to well-defined nanoscale (< 20 nm) interpenetrating networks (see figure). The power spectral density provides a detailed and quantitative description of the bulk heterojunction material and the kinetics of the phase separation.
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页码:1387 / +
页数:5
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