A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand

被引：30

作者：

Chandrasekhar, V ^{[1
]}

Azhakar, R

Bickley, JF

Steiner, A

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 04期

关键词：

D O I：

10.1039/b414353a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel linear trinuclear magnesium complex {P(S)[N(CH3)N=CHC6H4-o-O](3)}(2)Mg-3 was prepared by the reaction of P(S)[N(CH3)N=CHC6H4-o-OH](3) with MgCl(2)(.)6H(2)O in the presence of triethylamine. The trinuclear magnesium complex is fluorescent in solution as well as in the solid-state.

引用

页码：459 / 461

页数：3

共 22 条

[11] Magnesium chemistry and biochemistry [J].

Maguire, ME ;

Cowan, JA .

BIOMETALS, 2002, 15 (03) :203-210

[12] Ansa versus spiro substitution of cyclophosphazenes: Is fluorination essential for ansa to spiro transformation of cyclophosphazenes? [J].

Muralidharan, K ;

Venugopalan, P ;

Elias, AJ .

INORGANIC CHEMISTRY, 2003, 42 (10) :3176-3182

[13] Synthesis and characterization of magnesium and zinc complexes of 1,4,7-triazacyclononane-N-acetate.: Potential models for the active site of RuBisCo [J].

Odom, D ;

Gramer, CJ ;

Young, VG ;

Hilderbrand, SA ;

Sherman, SE .

INORGANICA CHIMICA ACTA, 2000, 297 (1-2) :404-410

[14] Structural implications of C-H•••S contacts in organophosphorus compounds.: Studies of 1,6-anhydro-2-O-tosyl-4-S-(5,5-dimethyl-2-thioxa-1,3,2-dioxaphosphorinan-2-yl)-β-D-glucopyranose by X-ray and solid-state NMR methods [J].

Potrzebowski, MJ ;

Michalska, M ;

Koziol, AE ;

Kazmierski, S ;

Lis, T ;

Pluskowski, J ;

Ciesielski, W .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (13) :4209-4217

[15] Electrochemiluminescence (ECL) [J].

Richter, MM .

CHEMICAL REVIEWS, 2004, 104 (06) :3003-3036

[16] Structural and catalytic roles for divalent magnesium in nucleic acid biochemistry [J].

Sreedhara, A ;

Cowan, JA .

BIOMETALS, 2002, 15 (03) :211-223

[17] C-H•••O hydrogen bonds in molecular complexes of 1,3,5-trinitrobenzene with some N-heterocycles [J].

Thallapally, PK ;

Katz, AK ;

Carrell, HL ;

Desiraju, GR .

CRYSTENGCOMM, 2003, :87-92

[18] Synthesis and structural studies on [Mg3(O2CC≡CSiMe3)6(HMPA)4]:: Mechanistic implications for the formation of the μ4-η4 bonding type in carbamato-bridged Mg6 cage compounds [J].

Yang, KC ;

Chang, CC ;

Yeh, CS ;

Lee, GH ;

Wang, Y .

ORGANOMETALLICS, 2002, 21 (06) :1296-1299

[19] Steric and solvent effects on the CO2 fixation of magnesium compounds [J].

Yang, KC ;

Chang, CC ;

Yeh, CS ;

Lee, GH ;

Peng, SM .

ORGANOMETALLICS, 2001, 20 (01) :126-137

[20]

YANG Z, POLYHEDRON, V15, P3771

← 1 2 3 →