Indium sulfide buffer/CIGSSe interface engineering:: Improved cell performance by the addition of zinc sulfide

被引:15
作者
Allsop, N. A. [1 ]
Camus, C. [1 ]
Haensel, A. [1 ]
Gledhill, S. E. [1 ]
Lauermann, I. [1 ]
Lux-Steiner, M. C. [1 ]
Fischer, Ch.-H. [1 ]
机构
[1] Hahn Meitner Inst Berlin GmbH, Dept SE2, D-14109 Berlin, Germany
关键词
solar cell; buffer layer; ILGAR; indium sulfide; zinc sulfide; CIGSSe; CIS; chalcopyrite;
D O I
10.1016/j.tsf.2006.12.084
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Indium sulfide buffer layers deposited by the spray-ion layer gas reaction (Spray-ILGAR) technique are a viable alternative to the traditional cadmium sulfide buffer layer in thin film solar cells. In the present work we report on the results of manipulating the absorber/buffer interface between the chalcopyrite Cu(In,Ga)(S,Se)(2) absorber (CIGSSe) and the indium sulfide buffer. It is shown that the deposition of a small amount of zinc sulfide at the absorber/buffer interface can be used to increase the open circuit voltage. A small but significant increase of 20 mV (up to 580 mV), as compared to the pure indium sulfide buffered cells is possible leading to an increase in the overall efficiency. (C) 2006 Elsevier B.V All rights reserved.
引用
收藏
页码:6068 / 6072
页数:5
相关论文
共 14 条
[1]   Interfacial layer formations between Cu(In,Ga)Se2 and InxSy layers -: art. no. 123512 [J].
Abou-Ras, D ;
Kostorz, G ;
Strohm, A ;
Schock, HW ;
Tiwari, AN .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (12)
[2]   The dry and damp heat stability of chalcopyrite solar cells prepared with an indium sulfide buffer deposited by the spray-ILGAR technique [J].
Allsop, N. A. ;
Haensel, A. ;
Visbeck, S. ;
Niesen, T. P. ;
Lux-Steiner, M. C. ;
Fischer, Ch. -H. .
THIN SOLID FILMS, 2006, 511 :55-59
[3]   Indium sulfide thin films deposited by the spray ion layer gas reaction technique [J].
Allsop, N. A. ;
Schoenmann, A. ;
Belaidi, A. ;
Muffler, H. -J. ;
Mertesacker, B. ;
Bohne, W. ;
Strub, E. ;
Roehrich, J. ;
Lux-Steiner, M. C. ;
Fischer, Ch. -H. .
THIN SOLID FILMS, 2006, 513 (1-2) :52-56
[4]  
ALLSOP NA, 2005, PROG PHOTOVOLT RES A, V13, P1
[5]   Formation of a ZnS/Zn(S,O) bilayer buffer on CuInS2 thin film solar cell absorbers by chemical bath deposition [J].
Baer, M. ;
Ennaoui, A. ;
Klaer, J. ;
Kropp, T. ;
Saez-Araoz, R. ;
Allsop, N. ;
Lauermann, I. ;
Schock, H. -W. ;
Lux-Steiner, M. C. .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (12)
[6]   The Berlin time-of-flight ERDA setup [J].
Bohne, W ;
Rohrich, J ;
Roschert, G .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1998, 136 :633-637
[7]  
Contreras MA, 2003, WORL CON PHOTOVOLT E, P570
[8]  
CURVE VA, MARKUS GLOECKLER
[9]   Highly efficient Cu(Ga,In)(S,Se)2 thin film solar cells with zinc-compound buffer layers [J].
Ennaoui, A ;
Eisele, W ;
Lux-Steiner, M ;
Niesen, TP ;
Karg, E .
THIN SOLID FILMS, 2003, 431 :335-339
[10]   High-efficiency copper indium gallium diselenide (CIGS) solar cells with indium sulfide buffer layers deposited by atomic layer chemical vapor deposition (ALCVD) [J].
Naghavi, N ;
Spiering, S ;
Powalla, M ;
Cavana, B ;
Lincot, D .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (07) :437-443