Synthesis and characterization of α,ω-heterofunctional poly(ethylene oxide) macromonomers

被引：21

作者：

Yilmaz, F

Cianga, I

Ito, K

Senyo, T

Yagci, Y

机构：

[1] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan

[2] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 04期

关键词：

free-radical polymerization; alpha; omega-heterofunctional polymers; macromonomers; oxidative polymerization;

D O I：

10.1002/marc.200390048

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel alpha,omega-heterofunctional poly(ethylene oxide) (PEO) macromonomer possessing methacryloyl and thienyl end groups was prepared by ring-opening polymerization of ethylene oxide initiated by potassium thienylethoxide and termination of the living PEO ends with methacryloyl chloride. Incorporation of methacryloyl and thienyl groups was confirmed by free-radical and oxidative polymerization processes, respectively, and by means of H-1 NMR analysis.

引用

页码：316 / 319

页数：4

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[12] Molecular composites from rigid-rod poly(p-phenylene)s with oligo(oxyethylene) side chains as novel polymer electrolytes [J].