Synthesis and structure of [(ButN)P(μ-NBut)2P(PCy)Li2•thf]2;: an unusual cage compound containing an amido/phosphido functionalised [(ButN)P(μ-NBut)2P(PCy)]2- dianion (Cy = C6H11)

被引：5

作者：

Bashall, A

Elvidge, BR

Beswick, MA

Kidd, SJ

McPartlin, M

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003468l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [((BuNH)-N-t)P(mu-NBut)(2)PCl] (1) with CyPHLi and (BuLi)-Li-n in toluene gives [((BuN)-N-t)P(mu-NBut)(2)P(PCy)Li-2. thf](2) (2), an unusual aggregate containing the first example of a phosphine-functionalised cyclodiphosphazane anion [((BuN)-N-t)P(mu-NBut)(2)P(PCy)](2-).

引用

页码：1439 / 1440

页数：2

共 22 条

[1] SYNTHESIS AND STRUCTURE OF [SB2LI2(N(C6H11))4]2 - A CAGE COMPLEX CONTAINING A CORE OF 2 INTERLOCKED BROKEN CUBES [J].

ALTON, RA ;

BARR, D ;

EDWARDS, AJ ;

PAVER, MA ;

RAITHBY, PR ;

RENNIE, MA ;

RUSSELL, CA ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (12) :1481-1482

[2]

BARR D, 1994, ANGEW CHEM INT EDIT, V33, P1875, DOI 10.1002/anie.199418751

[3]

BARR D, 1996, INORG CHIM ACTA, V248, P9

[4] A synthetic and structural study of the formation of cyclic [(RP)nE]- anions and Zintl compounds using E(NMe2)3 (E = As, Sb) [J].

Bashall, A ;

Beswick, MA ;

Choi, N ;

Hopkins, AD ;

Kidd, SJ ;

Lawson, YG ;

Mosquera, MEG ;

McPartlin, M ;

Raithby, PR ;

Wheatley, AAEH ;

Wood, JA ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04) :479-486

[5] Geometric control of cage architecture;: observation of ligand-selective behaviour in the structures of [{As2(NCy)4}2M4] (M = Na, Cu; Cy = C6H11) [J].

Bashall, A ;

Beswick, MA ;

Harron, EA ;

Hopkins, AD ;

Kidd, SJ ;

McPartlin, M ;

Raithby, PR ;

Steiner, A ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 1999, (12) :1145-1146

[6] Synthetic applications of p block metal dimethylamido reagents [J].

Beswick, MA ;

Wright, DS .

COORDINATION CHEMISTRY REVIEWS, 1998, 176 :373-406

[7] Assembly of mixed-metal cages using polyimido antimony(III) anions. Syntheses and structures of [Sb-3(NCy)(4)(HNCy)(2)]K center dot 2(toluene), [Sb-2(NCy)(4)](2)M-4 (M=Cu, Ag), and [Sb(NCy)(3)](2)Pb-3 (Cy equals cyclohexyl, C6H11) [J].

Beswick, MA ;

Cromhout, NL ;

Harmer, CN ;

Paver, MA ;

Raithby, PR ;

Rennie, MA ;

Steiner, A ;

Wright, DS .

INORGANIC CHEMISTRY, 1997, 36 (09) :1740-1744

[8] Direct synthesis of heterocyclic [(RP)nE]- anions using [E(NMe2)3] (E = Sb, As);: implications to the mechanism of formation of Zintl compounds [J].

Beswick, MA ;

Choi, N ;

Hopkins, AD ;

McPartlin, M ;

Mosquera, MEG ;

Raithby, PR ;

Rothenberger, A ;

Stalke, D ;

Wheatley, AJ ;

Wright, DS .

CHEMICAL COMMUNICATIONS, 1998, (22) :2485-2486

[9]

Beswick MA, 1997, CHEM COMMUN, P1879

[10] Synthesis and structure of [{As2(NCy)4}2Li4], containing an imido As(III) dianion [J].

Beswick, MA ;

Harron, EA ;

Hopkins, D ;

Raithby, PR ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (02) :107-108

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