Synthetic applications of p block metal dimethylamido reagents

被引：99

作者：

Beswick, MA ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 176卷

关键词：

dimethylamido; p block; cages; imido; phosphinidene;

D O I：

10.1016/S0010-8545(98)00126-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of dimethylamido p block metal reagents with primary amines (RNH2) and primary amido and phosphido alkali metal complexes ([REHM]; E = N, P; M = alkali metal) furnish direct routes to a range of imido and phosphinidene compounds. In particular, novel p block metal polyimido and phosphinidene anions are readily accessible from these reactions. These function as versatile ligands to a variety of main group and transition metals, giving a structured approach to the assembly of heterometallic complexes containing a broad spectrum of mixed-metal stoichiometries. This review describes the synthetic applications of p block metal dimethylamido reagents to a range of p block metal compounds and the structures and reactivities of the imido and phosphinidene complexes produced. (C) 1998 EIsevier Science S.A. All rights reserved.

引用

页码：373 / 406

页数：34

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