Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules

被引：63

作者：

Amaya, Toru

Mori, Koichi

Wu, Hsyueh-Liang

Ishida, Satoshi

Nakamura, Jun-ichi

Murata, Kazuhiko

Hirao, Toshikazu

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Nippon Shokubai Co Ltd, Adv Technol Res Ctr, Osaka 5648512, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 19期

关键词：

D O I：

10.1039/b701322a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of pi-extended bowl-shaped pi-conjugated compounds were synthesized from sumanene and characterized, and among them the terthiophene derivative showed a remarkable red-shifted absorption and small band gap, which was rationalized by molecular orbital calculation.

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收藏

页码：1902 / 1904

页数：3

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