Synthesis of filled skutterudite compounds:: BayFexCo4-xSb12

被引：51

作者：

Chen, L ^{[1
]}

Tang, X ^{[1
]}

Goto, T ^{[1
]}

Hirai, T ^{[1
]}

机构：

[1] Tohoku Univ, Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

JOURNAL OF MATERIALS RESEARCH | 2000年 / 15卷 / 11期

关键词：

D O I：

10.1557/JMR.2000.0325

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ba-filled skutterudite compounds, BayFexCo4-xSb12, were synthesized by a two-step solid reaction method. A binary compound of Sb3Ba and a ternary compound of FexCo1-xSb2 were first synthesized at 900 and 973 K, respectively. The presynthesized Sb3Ba and FexCo1-xSb2 were then mixed with Sb and heated at 973 K in an Ar atmosphere. The resulting powder was of single phase with a composition of BayFexCo4-xSb12, having skutterudite structure with the Sb-dodecahedron voids fractionally filled by Ba. The lattice constant of BayFexCo4-xSb12 increased with Ba and Fe content. The maximum filling fraction of Ba (y(max)) in BayFexCo4-xSb12 was found to be greater than that of Ce or La in Ln(y)Fe(x)Co(4-x)Sb(12), especially in the lower Fe content region. The y(max) varied from 0.35 to near 1.0 when Fe content (x) changed from 0 to 4.

引用

页码：2276 / 2279

页数：4

共 15 条

[11] Filled skutterudite antimonides: A new class of thermoelectric materials [J].

Sales, BC ;

Mandrus, D ;

Williams, RK .

SCIENCE, 1996, 272 (5266) :1325-1328

[12] STRUCTURE REFINEMENT OF SKUTTERUDITE-TYPE COBALT TRIANTIMONIDE, COSB3 [J].

SCHMIDT, T ;

KLICHE, G ;

LUTZ, HD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1678-1679

[13] Calculated thermoelectric properties of La-filled skutterudites [J].

Singh, DJ ;

Mazin, II .

PHYSICAL REVIEW B, 1997, 56 (04) :R1650-R1653

[14] THE SYNTHESIS AND STRUCTURE OF 2 FILLED SKUTTERUDITE COMPOUNDS - BAFE4SB12 AND BARU4SB12 [J].

STETSON, NT ;

KAUZLARICH, SM ;

HOPE, H .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 91 (01) :140-147

[15] Thermoelectric properties of CeyFexCo4-xSb12 prepared by a solid state reaction [J].

Tang, XF ;

Chen, LD ;

Goto, T ;

Hirai, T .

JOURNAL OF THE JAPAN INSTITUTE OF METALS, 1999, 63 (11) :1412-1415

← 1 2 →