Electrocatalytic dimerisation of non-heteroatom-substituted manganese alkynylcarbene complexes

被引：23

作者：

Ortin, Y ^{[1
]}

Sournia-Saquet, A ^{[1
]}

Lugan, N ^{[1
]}

Mathieu, R ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 09期

关键词：

D O I：

10.1039/b300623a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon controlled potential electrolysis (-1.30 V vs. SCE), the alkynylcarbene complexes MeCp(CO)(2)Mn=NC(R)C=CR' are seen to undergo an electrocatalytic dimerisation by coupling of the remote alkynyl carbon atoms to afford the ene-diyne dimanganese complexes [MeCp(CO)(2)Mn](2)[eta(4)-(E)-RC=C(R')C=C(R')C=CR].

引用

页码：1060 / 1061

页数：2

共 18 条

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