A new approach for the determination of the absolute configuration of secondary alcohols by 1H NMR with O-substituted mandelate derivatives.

被引：44

作者：

Chataigner, I ^{[1
]}

Lebreton, J ^{[1
]}

Durand, D ^{[1
]}

Guingant, A ^{[1
]}

Villiéras, J ^{[1
]}

机构：

[1] Fac Sci & Tech, Synth Organ Lab, CNRS, UMR 6513, F-44322 Nantes 3, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(98)00059-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is shown that the cheap and easily prepared mandelic acid esters (or their OAc analogues) are best suited than the expensive, although usually employed, OMe mandelic acid esters to assess both the enantiomeric excesses and absolute configurations of secondary alcohols. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1759 / 1762

页数：4

共 24 条

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