Metal-mediated and metal-catalyzed hydrolysis of nitriles

被引：378

作者：

Kukushkin, VY

Pombeiro, AJL

机构：

[1] St Petersburg State Univ, Dept Chem, St Petersburg 198904, Russia

[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 01期

关键词：

D O I：

10.1016/j.ica.2004.04.029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The essential goals of this review are the following: (i) to verify various factors which affect the metal-mediated hydrolysis of organonitriles; (ii) to draw attention to unusual conversions of RCN species, yet underdeveloped and non-systematic, which involve hydrolysis and lead to compounds of synthetic and/or pharmacological significance. The metal-mediated and/or metal-catalyzed reactions of RCN species are surveyed and the experimental material on metal-mediated hydration of RCN species at diverse metal centers along the Periodic Table is summarized in a tabular form. (C) 2004 Elsevier B.V. All rights reserved.

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页码：1 / 21

页数：21

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