Metal-mediated and metal-catalyzed hydrolysis of nitriles

被引:378
作者
Kukushkin, VY
Pombeiro, AJL
机构
[1] St Petersburg State Univ, Dept Chem, St Petersburg 198904, Russia
[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal
关键词
D O I
10.1016/j.ica.2004.04.029
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The essential goals of this review are the following: (i) to verify various factors which affect the metal-mediated hydrolysis of organonitriles; (ii) to draw attention to unusual conversions of RCN species, yet underdeveloped and non-systematic, which involve hydrolysis and lead to compounds of synthetic and/or pharmacological significance. The metal-mediated and/or metal-catalyzed reactions of RCN species are surveyed and the experimental material on metal-mediated hydration of RCN species at diverse metal centers along the Periodic Table is summarized in a tabular form. (C) 2004 Elsevier B.V. All rights reserved.
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页码:1 / 21
页数:21
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