Synthesis of enantiopure 3-hydroxymethylchromanes via intramolecular nitrone cycloaddition

被引：34

作者：

Broggini, G

Folcio, F

Sardone, N

Sonzogni, M

Zecchi, G

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

[2] UNIV PAVIA,CTR GRANDI STRUMENTI,I-27100 PAVIA,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 03期

关键词：

D O I：

10.1016/0957-4166(96)00076-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiopure (R) and (S) 3-hydroxymethylchromanes were prepared by the intramolecular nitrone cycloaddition strategy, starting from allyl-type ethers of 2-hydroxybenzaldehydes and using (R)-N-(alpha-phenylethyl)hydroxylamine as chiral auxiliary.

引用

页码：797 / 806

页数：10