Electrodeposited PEDOT films on ITO with a flower-like hierarchical structure

被引：49

作者：

Zhou, Cuifeng ^{[2
]}

Liu, Zongwen ^{[2
]}

Du, Xusheng ^{[1
]}

Ringer, Simon P. ^{[2
]}

机构：

[1] Univ Sydney, Sch Aerosp Mech & Mech Engn, Sydney, NSW 2006, Australia

[2] Univ Sydney, Australian Key Ctr Microanal & Microscopy, Sydney, NSW 2006, Australia

来源：

SYNTHETIC METALS | 2010年 / 160卷 / 15-16期

基金：

澳大利亚研究理事会;

关键词：

PEDOT; Conductive polymer; SEM; Electro-polymerization; Nanostructure; INCORPORATED POLY(3,4-ETHYLENEDIOXYTHIOPHENE); POLY 3,4-ETHYLENEDIOXYTHIOPHENE; CAMPHORSULFONIC ACID; CONDUCTING POLYMERS; MICELLAR-SOLUTION; POLYMERIZATION; POLYPYRROLE; ELECTROSYNTHESIS; NANOMATERIALS; ACETONITRILE;

D O I：

10.1016/j.synthmet.2010.05.033

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(3,4-ethylenedioxythiophene) (PEDOT) films with a flower-like nanostructure have been electrochemically deposited on indium tin oxide (ITO) electrode simply by a one-step cyclic voltammetry (CV) method in an aqueous media in the absence of any surfactant. The PEDOT films deposited on the substrates were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. The results indicate that the flower-like hierarchical structure of the PEDOT film is composed of nanosheets with a thickness of even less than 2 nm at the edge. The resulted porous structure of the PEDOT coating leads to a two-order increase of magnitude in the electrochemical capacitance-current. The growth process of the electrodeposited PEDOT as well as the effect of polymerization potential on the properties of products was studied. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1636 / 1641

页数：6

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