Addition of the ortho-C-H bonds of phenol across an olefin catalysed by a chiral iridium(I) diphosphine complex

被引:97
作者
Dorta, R [1 ]
Togni, A
机构
[1] Univ Simon Bolivar, Dept Quim, Caracas 1080A, Venezuela
[2] ETH Honggerberg, Swiss Fed Inst Technol, Dept Chem, CH-8093 Zurich, Switzerland
关键词
D O I
10.1039/b211672c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chiral iridium(I) diphosphine complex efficiently catalyses the unprecedented ortho-alkylation of phenol with norbornene in the absence of solvent leading to the formation of one and two C-C bonds.
引用
收藏
页码:760 / 761
页数:2
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