Reaction kinetics of C60 fullerene ozonation

被引：17

作者：

Anachkov, MP

Cataldo, F

Rakovsky, SK

机构：

[1] Soc Lupi Chem Res Inst, I-00133 Rome, Italy

[2] Bulgarian Acad Sci, Inst Catalysis, Sofia, Bulgaria

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2003年 / 11卷 / 02期

关键词：

fullerene; ozone; kinetics; rate constant;

D O I：

10.1081/FST-120021136

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It has been verified that the reaction between O-3 and C-60 follows the general second order reaction rate which is valid for all the reactions between ozone and unsaturated olefinic bonds: v=k[C=C][O-3]. The reaction rate constant k has been measured approximate to(1.5 +/- 0.3)x 10(4) L mol(-1) s(-1). The value of this rate constant has the same order of magnitude of the rate constant measured for instance in the ozonation of 1,4-diphenylbutadiene.

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收藏

页码：95 / 103

页数：9

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