Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands.: The X-ray crystal structure of (-)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}-phenyl]chloroplatinum(II)

被引：19

作者：

Donkervoort, JG

Vicario, JL

Jastrzebski, JTBH

Smeets, WJJ

Spek, AL

van Koten, G

机构：

[1] Univ Utrecht, Dept Met Mediated Synth, Debye Inst, NL-3584 CH Utrecht, Netherlands

[2] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 551卷 / 1-2期

关键词：

(-)-[(1R; 1; R)-bis(1-(dimethylamino)propyl)phenyl]chloroplatinum(II); arylplatinum(II); chiral monoanionic aryldiamine ligands;

D O I：

10.1016/S0022-328X(97)00247-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new chiral arylplatinum(II) compounds [2,6-bis(1-(dimethylamino)ethyl)phenyl]chloroplatinum (4) and (-)-[(1R,1'R)-bis(1-(dimethylamino)propyl)phenyl]chloroplatinum(II) (5) have been synthesized. The transmetallation of the corresponding aryllithium compounds does not affect either stereogenic centres of the organic ligand while the rate of the transmetallation is shown to be influenced by the size of the benzylic substituents. The X-ray crystal structure of 5 is reported from which the absolute configuration of both stereogenic centres of the organic ligand was determined to be (R). (C) 1998 Elsevier Science B.V.

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页码：1 / 7

页数：7

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