Use of Winterfeldt's template to control the C-2′ configuration in the synthesis of strigol-type compounds

被引：19

作者：

Röhrig, S

Hennig, L

Findeisen, M

Welzel, P

Müller, D

机构：

[1] Univ Leipzig, Fak Chem & Mineral, D-04103 Leipzig, Germany

[2] Ruhr Univ Bochum, Fak Chem, D-44780 Bochum, Germany

来源：

TETRAHEDRON | 1998年 / 54卷 / 14期

关键词：

D O I：

10.1016/S0040-4020(98)00077-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A route comprising (i) a cycloaddition reaction of citraconic anhydride with the Winterfeldt auxiliary, (ii) hydride reduction of the cycloadduct, (iii) a (formal) ether formation, and (iv) a cycloreversion reaction allows efficient stereocontrol at C-2' in the synthesis of strigol and its structural analogues. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3439 / 3456

页数：18