The nature of the counter-anion can determine the rate of water exchange in a metal aqua complex

被引：30

作者：

Barge, A

Botta, M

Parker, D

Puschmann, H

机构：

[1] Univ Piemonte Orientale, Dipartimento Sci & Tecnol Avanzate, I-10131 Alessandria, Italy

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 12期

关键词：

D O I：

10.1039/b302211k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nature of the counter-anion determines the water exchange rate for a series of cationic gadolinium complexes in aqueous solution, as a consequence of the ordering effect that the anion imposes on the structure of the second hydration sphere.

引用

页码：1386 / 1387

页数：2

共 21 条

[1] Dependence of the relaxivity and luminescence of gadolinium and europium amino-acid complexes on hydrogencarbonate and pH
Aime, S
Barge, A
Botta, M
Howard, JAK
Kataky, R
Lowe, MP
Moloney, JM
Parker, D
de Sousa, AS
[J]. CHEMICAL COMMUNICATIONS, 1999, (11) : 1047 - 1048
[2] Prototropic vs whole water exchange contributions to the solvent relaxation enhancement in the aqueous solution of a cationic Gd3+ macrocyclic complex
Aime, S
Barge, A
Botta, M
Parker, D
DeSousa, AS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (20) : 4767 - 4768
[3] Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes
Aime, S
Barge, A
Batsanov, AS
Botta, M
Delli Castelli, D
Fedeli, F
Mortillaro, A
Parker, D
Puschmann, H
[J]. CHEMICAL COMMUNICATIONS, 2002, (10) : 1120 - 1121
[4] NMR, relaxometric, and structural studies of the hydration and exchange dynamics of cationic lanthanide complexes of macrocyclic tetraamide ligands
Aime, S
Barge, A
Bruce, JI
Botta, M
Howard, JAK
Moloney, JM
Parker, D
de Sousa, AS
Woods, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (24) : 5762 - 5771
[5] BLEMZEN A, 1996, J AM CHEM SOC, V118, P12777
[6] Botta M, 2000, EUR J INORG CHEM, P399
[7] The Hofmeister series: salt and solvent effects on interfacial phenomena
Cacace, MG
Landau, EM
Ramsden, JJ
[J]. QUARTERLY REVIEWS OF BIOPHYSICS, 1997, 30 (03) : 241 - 277
[8] Gadolinium(III) chelates as MRI contrast agents: Structure, dynamics, and applications
Caravan, P
Ellison, JJ
McMurry, TJ
Lauffer, RB
[J]. CHEMICAL REVIEWS, 1999, 99 (09) : 2293 - 2352
[9] Charge density-dependent strength of hydration and biological structure
Collins, KD
[J]. BIOPHYSICAL JOURNAL, 1997, 72 (01) : 65 - 76
[10] HIGH-PRESSURE NMR-STUDY .38. WATER-EXCHANGE MECHANISMS ON THE TERBIUM TO THULIUM OCTAAQUALANTHANIDE(III) IONS - A VARIABLE-PRESSURE O-17 NMR-STUDY
COSSY, C
HELM, L
MERBACH, AE
[J]. INORGANIC CHEMISTRY, 1989, 28 (14) : 2699 - 2703

← 1 2 3 →