Simultaneous absorption of SO2 and no in a stirred tank reactor with NACLO2/NAOH solutions

被引:24
作者
Chu, H [1 ]
Chien, TW [1 ]
Twu, BW [1 ]
机构
[1] Natl Cheng Kung Univ, Dept Environm Engn, Tainan 70101, Taiwan
关键词
absorption; flue gas; nitrogen oxides; sodium chlorite; sodium hydroxide; stirred tank reactor; sulfur dioxide;
D O I
10.1023/A:1022838623521
中图分类号
X [环境科学、安全科学];
学科分类号
08 [工学]; 0830 [环境科学与工程];
摘要
The wet scrubbing combined SOX/NO removal system is one of the advanced air pollution control devices. This study tries to understand the kinetics of the absorption in the system. The absorption of SO2 and simultaneous absorption of SO2 and NO, whose concentrations are typical for flue gases emitted from coal-fired power plants, in a stirred tank reactor with NaClO2/NaOH solutions were carried out at 50 degreesC. The liquid-side and gas-side mass transfer coefficients of the system were determined. The results indicate that the absorption of SO2 is completely gas-film controlled if the NaOH concentration is greater than 0.1 M or the NaClO2 concentration is greater than 0.2 M. Adding SO2 would decrease the absorption rate of NO; however, the addition of NO has no effect on the absorption rate of SO2. The existence of O-2 has no significant effect on the absorption rate of SO2 and NO in the combined SOX/NO removal tests.
引用
收藏
页码:337 / 350
页数:14
相关论文
共 22 条
[1]
Bird R.B., 2006, TRANSPORT PHENOMENA, Vsecond, DOI 10.1002/aic.690070245
[2]
LBL PHOSNOX PROCESS FOR COMBINED REMOVAL OF SO2 AND NOX FROM FLUE-GAS [J].
CHANG, SG ;
LEE, GC .
ENVIRONMENTAL PROGRESS, 1992, 11 (01) :66-73
[3]
Removal of SO2 and NO from flue gas by wet scrubbing using an aqueous NaClO2 solution [J].
Chien, TW ;
Chu, H .
JOURNAL OF HAZARDOUS MATERIALS, 2000, 80 (1-3) :43-57
[4]
Spray scrubbing of the nitrogen oxides into NaClO2 solution under acidic conditions [J].
Chien, TW ;
Chu, H ;
Hsueh, HT .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2001, 36 (04) :403-414
[5]
Simultaneous absorption of SO2 and NO from flue gas with KMnO4/NaOH solutions [J].
Chu, H ;
Chien, TW ;
Li, SY .
SCIENCE OF THE TOTAL ENVIRONMENT, 2001, 275 (1-3) :127-135
[6]
The absorption kinetics of NO from flue gas in a stirred tank reactor with KMnO4/NaOH solutions [J].
Chu, H ;
Li, SY ;
Chien, TW .
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 1998, 33 (05) :801-827
[7]
The absorption kinetics of NO in NaClO2/NaOH solutions [J].
Chu, H ;
Chien, TW ;
Twu, BW .
JOURNAL OF HAZARDOUS MATERIALS, 2001, 84 (2-3) :241-252
[8]
REMOVAL OF NITROGEN-OXIDES WITH AQUEOUS-SOLUTIONS OF INORGANIC AND ORGANIC-REAGENTS [J].
KOBAYASHI, H ;
TAKEZAWA, N ;
NIKI, T .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1977, 11 (02) :190-192
[9]
LI L, 1993, NITROGEN OXIDES REMO
[10]
Makansi J., 1990, Power, V134, P26