Probing mechanistic features of conventional, catalytic and living free radical polymerizations using soft ionization mass spectrometric techniques

被引：104

作者：

Barner-Kowollik, C ^{[1
]}

Davis, TP ^{[1
]}

Stenzel, MH ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn & Ind Chem, CAMD, Sydney, NSW 2052, Australia

来源：

POLYMER | 2004年 / 45卷 / 23期

基金：

澳大利亚研究理事会;

关键词：

electrospray ionization mass spectrometry; matrix assisted laser desorption ionization-time of flight mass spectrometry; free radical polymerization mechanism and kinetics;

D O I：

10.1016/j.polymer.2004.09.017

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present feature article provides an overview on the use of state-of-the-art mass spectrometry techniques such as matrix assisted laser desorption and ionization time of flight (MALDI-TOF) mass spectrometry as well as electrospray ionization mass spectrometry (ESI-MS) for probing the mechanism of free radical polymerization processes. The article features representative examples of the application of mass spectrometry techniques to conventional free radical polymerization, nitroxide mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT) as well as catalytic chain transfer (CCT) processes. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7791 / 7805

页数：15

共 132 条

[61]

JASIECZEK CB, 1996, AM CHEM SOC POLYM PR, V37, P451

[62] The quadrupole ion trap mass spectrometer - A small solution to a big challenge [J].

Jonscher, KR ;

Yates, JR .

ANALYTICAL BIOCHEMISTRY, 1997, 244 (01) :1-15

[63]

Kapfenstein HM, 1998, MACROMOL CHEM PHYSIC, V199, P2403, DOI 10.1002/macp.1998.021991106

[64] POLYMERIZATION OF METHYL-METHACRYLATE WITH THE CARBON-TETRACHLORIDE DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) METHYLALUMINUM BIS(2,6-DI-TERT-BUTYLPHENOXIDE) INITIATING SYSTEM - POSSIBILITY OF LIVING RADICAL POLYMERIZATION [J].

KATO, M ;

KAMIGAITO, M ;

SAWAMOTO, M ;

HIGASHIMURA, T .

MACROMOLECULES, 1995, 28 (05) :1721-1723

[65] MASS-SPECTROMETRIC SEQUENCING OF LINEAR PEPTIDES BY PRODUCT-ION ANALYSIS IN A REFLECTRON TIME-OF-FLIGHT MASS-SPECTROMETER USING MATRIX-ASSISTED LASER-DESORPTION IONIZATION [J].

KAUFMANN, R ;

SPENGLER, B ;

LUTZENKIRCHEN, F .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1993, 7 (10) :902-910

[66]

KOWOLLIK C, 1999, THESIS GOTTINGEN

[67] Copolymerization of styrene and α-methylstyrene in the presence of a catalytic chain transfer agent [J].

Kukulj, D ;

Heuts, JPA ;

Davis, TP .

MACROMOLECULES, 1998, 31 (18) :6034-6041

[68] Chain transfer to monomer in the free-radical polymerizations of methyl methacrylate, styrene, and α-methylstyrene [J].

Kukulj, D ;

Davis, TP ;

Gilbert, RG .

MACROMOLECULES, 1998, 31 (04) :994-999

[69]

Kukulj D, 1997, J POLYM SCI POL CHEM, V35, P859, DOI 10.1002/(SICI)1099-0518(19970415)35:5<859::AID-POLA2>3.0.CO

[70]

2-G

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