Electrochemical reduction of an imidazolium cation: a convenient preparation of imidazol-2-ylidenes and their observation in an ionic liquid

被引：148

作者：

Gorodetsky, B ^{[1
]}

Ramnial, T ^{[1
]}

Branda, NR ^{[1
]}

Clyburne, JAC ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 17期

关键词：

D O I：

10.1039/b407386j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Bis(2,4,6-trimethylphenyl) imidazolium chloride is reduced electrochemically and chemically to produce a nucleophilic carbene, namely 1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene. The carbene was also shown to be compatible with and persistent in the ionic liquid tetradecyl(trihexyl) phosphonium chloride.

引用

页码：1972 / 1973

页数：2

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