Synthesis and characterization of heterodinuclear thiolate complexes containing the Pd(η3-allyl)+ moiety.: Crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4]

被引：16

作者：

Ruiz, J

Giner, J

Rodríguez, V

López, G ^{[1
]}

Casabó, J

Molins, E

Miravitlles, C

机构：

[1] Univ Murcia, Dept Quim Inorgan, E-30071 Murcia, Spain

[2] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

[3] CSIC, Inst Ciencia Mat Barcelona, E-08193 Barcelona, Spain

来源：

POLYHEDRON | 2000年 / 19卷 / 13期

关键词：

palladium; platinum; thiolate complexes; allyl complexes;

D O I：

10.1016/S0277-5387(00)00440-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hetero dinuclear complexes of the types [(dppe)M(mu-SR)(2)Pd(eta(3)-allyl)][ClO4] (M = Pd or Pt) and [(dppe)Pt(mu-SC2H4S)Pd(eta(3)-allyl)][ClO4] [dppe = 1,2-bis(diphenylphosphino)ethane; allyl = C3H5 or C4H7] have been obtained by reaction of the corresponding cis-dithiolato complexes, [M(SR)(2) (dppe)] or [Pt(SC2H4S)(dppe)]. and [Pd(eta(3)-allyl)(PhCN)(2)][ClO4]. The identity of these complexes has been established by NMR (H-1 and P-31) spectroscopy. The crystal structure of [(dppe)Pd(mu-SC6H4Me-p)(2)Pd(eta(3)-C3H5)][ClO4] has been determined by single-crystal X-ray methods. The p-tolyl groups on the sulfur atoms adopt a syn conformation with respect to the central Pd-S-2-Pd core. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1627 / 1631

页数：5

共 21 条

[1] SYNTHESIS AND CHARACTERIZATION OF THIOLATO-BRIDGED TITANIUM-PLATINUM AND TITANIUM-PALLADIUM HETEROBINUCLEAR COMPLEXES - MOLECULAR-STRUCTURE OF [(ETA(5)-C(5)H(4)SIME(3))(2)TI(MU-SPH)(2)PD(C6F5)(2)] [J].