Corrole synthesis by dipyrromethane-dicarbinol and 2,2′-bipyrrole condensation

被引:45
作者
Decréau, RA [1 ]
Collman, JP [1 ]
机构
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
基金
美国国家科学基金会;
关键词
dipyrromethane-dicarbinol; 2,2 '-bipyrrole; corrole synthesis;
D O I
10.1016/S0040-4039(03)00617-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A(3) and trans-A(2)B tris-aryl corroles 1a-c have been synthesized in up to 12% yield by BF3.Et2O-catalyzed condensation of dipyrromethane-dicarbinol and 2,2'-bipyrrole (1:1 ratio) in acetonitrile at room temperature for 24 h. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3323 / 3327
页数:5
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