Metalorganic chemical vapor deposition of conductive CaRuO3 thin films

被引:24
作者
Higashi, N [1 ]
Okuda, N [1 ]
Funakubo, H [1 ]
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Innovat & Engn Mat, Midori Ku, Yokohama, Kanagawa 2268502, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 2000年 / 39卷 / 5A期
关键词
MOCVD; CaRuO3; conductive oxide; resistivity; perovskite structure; epitaxial; lattice mismatch;
D O I
10.1143/JJAP.39.2780
中图分类号
O59 [应用物理学];
学科分类号
摘要
CaRuO3 thin films expected for use as an electrode of ferroelectric random-access memory were prepared for the first time by metalorganic chemical vapor deposition (MOCVD) from the bis(dipivaloylmethanato)calcium(tetraen) [Ca(C11H29O2)(2)(C8H23N5)(x)]-tris(dipivaloylmethanato)ruthenium [Ru(C11H29O2)(3)]-O-2 and the bis(dipivaloylmethanato)calcium(tetraen) [Ca(C11H29O2)(2)(C8H23N5)(x)]-bis(ethylcyclipentadienyl)ruthenium Ru[(C5H4)(C2H5)](2)-O-2 systems. Epitaxial films were obtained on (100)LaAlO3 and (100)SrTiO3 substrates at 750 degrees C, while randomly oriented films were obtained on a (100)MgO substrate. The resistivity of these films was about 200 mu Omega.cm, and was confirmed to be independent of film thickness ranging from 70 to 300 nm. This value is lower than that of SrRuO3 thin films, about 280 mu Omega.cm.
引用
收藏
页码:2780 / 2783
页数:4
相关论文
共 13 条
[1]   ELECTRICAL PROPERTIES OF CARUO3 AND SRRUO3 SINGLE-CRYSTALS [J].
BOUCHARD, RJ ;
GILLSON, JL .
MATERIALS RESEARCH BULLETIN, 1972, 7 (09) :873-&
[2]   Characterization of sol-gel PZT capacitors with SrRuO3 and Pt electrodes [J].
Cross, JS ;
Fujiki, M ;
Sakai, T ;
Tsukada, M ;
Kamehara, N .
ELECTROCERAMICS IN JAPAN I, 1999, 157-1 :181-187
[3]   SINGLE-CRYSTAL EPITAXIAL THIN-FILMS OF THE ISOTROPIC METALLIC OXIDES SR1-XCAXRUO3 (0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1) [J].
EOM, CB ;
CAVA, RJ ;
FLEMING, RM ;
PHILLIPS, JM ;
VANDOVER, RB ;
MARSHALL, JH ;
HSU, JWP ;
KRAJEWSKI, JJ ;
PECK, WF .
SCIENCE, 1992, 258 (5089) :1766-1769
[4]   Degradation-free ferroelectric Pb(Zr,Ti)O3 thin film capacitors with IrO2 top electrode [J].
Fujisaki, Y ;
Kushida-Abdelghafar, K ;
Miki, H ;
Shimamoto, Y .
INTEGRATED FERROELECTRICS, 1998, 21 (1-4) :83-95
[5]   ON THE MAGNETISM AND ELECTRONIC CONDUCTION OF ITINERANT MAGNETIC SYSTEM CA1-XSRXRUO3 [J].
FUKUNAGA, F ;
TSUDA, N .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1994, 63 (10) :3798-3807
[6]   Ti and Ca substitution in SrRuO3 thin films by sequential deposition process [J].
Mieville, L ;
Geballe, TH ;
Antognazza, L ;
Char, K .
APPLIED PHYSICS LETTERS, 1997, 70 (01) :126-128
[7]   Low-temperature deposition of SrRuO3 thin film prepared by metalorganic chemical vapor deposition [J].
Okuda, N ;
Saito, K ;
Funakubo, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (2A) :572-576
[8]  
Okuda N., 1999, T MAT RES SOC JPN, V24, P51
[9]   PRESSURE-DEPENDENCE OF THE MAGNETIC TRANSITION-TEMPERATURE FOR FERROMAGNETIC SRRUO3 [J].
SHIKANO, M ;
HUANG, TK ;
INAGUMA, Y ;
ITOH, M ;
NAKAMURA, T .
SOLID STATE COMMUNICATIONS, 1994, 90 (02) :115-119
[10]  
SPITSYN VI, 1973, RUSS J INORG CHEM, V18, P592