Hydrogen Generation from Formic Acid Decomposition with a Ruthenium Catalyst Promoted by Functionalized Ionic Liquids

被引：57

作者：

Li, Xueli ^{[1
,2
]}

Ma, Xiangyuan ^{[1
]}

Shi, Feng ^{[1
]}

Deng, Youquan ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

CHEMSUSCHEM | 2010年 / 3卷 / 01期

基金：

中国国家自然科学基金;

关键词：

catalysis; formic acid; fuel cells; hydrogen; ionic liquids; CARBON-DIOXIDE; COMPLEX CATALYST; STORAGE MATERIAL; FUEL-CELLS; FUTURE; CO2; ACTIVATION;

D O I：

10.1002/cssc.200900218

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of amine-functionalized ionic liquids is prepared and used for hydrogen generation by the selective catalytic decomposition of formic acid. A good catalytic activity was obtained using an iPr2NEMimCl HCOONa system at 40°C. The use of volatile organic amines is thus avoided, simplifying the purification of hydrogen. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：71 / 74

页数：4

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