Femtosecond solvation dynamics of the hydrated electron

被引：201

作者：

Silva, C ^{[1
]}

Walhout, PK ^{[1
]}

Yokoyama, K ^{[1
]}

Barbara, PF ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

PHYSICAL REVIEW LETTERS | 1998年 / 80卷 / 05期

关键词：

D O I：

10.1103/PhysRevLett.80.1086

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Femtosecond pump-probe spectroscopy of the equilibrated hydrated electron has been recorded with 35 Ps resolution, revealing unprecedented transient features on the 30-80 fs time scales that have been assigned to inertial solvation dynamics of the hydrated electron. These data allow for a rigorous experimental evaluation of the recently published nonadiabatic quantum molecular dynamics simulations of the adiabatic and nonadiabatic dynamics of the hydrated electron. [S0031-9007(98)05313-7].

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页码：1086 / 1089

页数：4

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