On the mechanism of catalytic, enantioselective allylation of aldehydes with chlorosilanes and chiral Lewis bases

被引：112

作者：

Denmark, SE ^{[1
]}

Fu, JP ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Roger Adams Lab, Urbana, IL 61801 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 48期

关键词：

D O I：

10.1021/ja002060a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：12021 / 12022

页数：2

共 37 条

[1]

Angell RM, 1997, CHEM COMMUN, P919

[2] Nonlinear stereochemical effects in asymmetric reactions [J].

Avalos, M ;

Babiano, R ;

Cintas, P ;

Jimenez, JL ;

Palacios, JC .

TETRAHEDRON-ASYMMETRY, 1997, 8 (18) :2997-3017

[3] Ureas: New efficient Lewis base catalysts for the allylation of aldehydes [J].

Chataigner, I ;

Piarulli, U ;

Gennari, C .

TETRAHEDRON LETTERS, 1999, 40 (18) :3633-3634

[4]

Denmark S. E., 2000, MODERN CARBONYL CHEM

[5] Enantioselective ring opening of epoxides with silicon tetrachloride in the presence of a chiral Lewis base [J].

Denmark, SE ;

Barsanti, PA ;

Wong, KT ;

Stavenger, RA .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (08) :2428-2429

[6] Solid state and solution structural studies of chiral phosphoramide-tin complexes relevant to Lewis base catalyzed aldol reactions [J].

Denmark, SE ;

Su, XP .

TETRAHEDRON, 1999, 55 (29) :8727-8738

[7] The chemistry of trichlorosilyl enolates. 6. Mechanistic duality in the Lewis base-catalyzed aldol addition reaction [J].

Denmark, SE ;

Su, XP ;

Nishigaichi, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (49) :12990-12991

[8] Chiral phosphoramide-catalyzed aldol additions of ketone enolates. Preparative aspects [J].

Denmark, SE ;

Stavenger, RA ;

Wong, KT ;

Su, XP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (21) :4982-4991

[9] ASYMMETRIC ALLYLATION OF ALDEHYDES WITH CHIRAL LEWIS-BASES [J].

DENMARK, SE ;

COE, DM ;

PRATT, NE ;

GRIEDEL, BD .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (21) :6161-6163

[10]

Denmark SE, 2000, HELV CHIM ACTA, V83, P1846, DOI 10.1002/1522-2675(20000809)83:8<1846::AID-HLCA1846>3.0.CO

← 1 2 3 4 →