Comparative analysis of volatile components from Clematis species growing in China

被引：77

作者：

Zeng, Ying-Xu

Zhao, Chen-Xi ^{[1
]}

Liang, Yi-Zeng

Yang, Hong

Fang, Hong-Zhuang

Yi, Lun-Zhao

Zeng, Zhong-Da

机构：

[1] Cent S Univ, Coll Chem & Chem Engn, Res Ctr Modernizat Chinese Herbal Med, Changsha 410083, Hunan, Peoples R China

[2] Changsha Univ, Dept Appl Chem & Environm Sci, Changsha 410003, Hunan, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2007年 / 595卷 / 1-2期

关键词：

essential oils; Clematis; gas chromatography-mass spectrometry (GC-MS); temperature-programmed retention indices (PTRIs); alternative moving window factor analysis (AMWFA);

D O I：

10.1016/j.aca.2006.12.022

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The volatile components between stems and roots and also among five Clematis species from China were studied and analyzed by gas chromatography-mass spectrometry (GC-MS) combined with alternative moving window factor analysis (AMWFA), a new chemometric resolution method. Identification of the compounds was also assisted by comparison of temperature-programmed retention indices (PTRIs) on HP-5MS with authentic samples included in our own laboratory database under construction. A total of 153 different compounds accounting for 86.6-96.5% were identified and significant qualitative and quantitative differences were observed among the samples. The major volatile components in different essential oils from Clematis species were n-hexadecanoic acid and (ZZ)-9,12-octadecadienoic acid. Our work further demonstrated chemornetric resolution techniques upon the two-dimensional data and PTRIs can provide a complementary and convenient method for fast and accurate analysis of complex essential oils. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：328 / 339

页数：12