Folding directed N-oxidation of oligopyridine-dicarboxamide strands and hybridization of oxidized oligomers

被引：85

作者：

Dolain, C

Zhan, CL

Léger, JM

Daniels, L

Huc, I

机构：

[1] Inst Europeen Chim & Biol, F-33607 Pessac, France

[2] Lab Pharmacochim, F-33076 Bordeaux, France

[3] Rigaku MSC Inc, The Woodlands, TX 77381 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 08期

关键词：

D O I：

10.1021/ja0424631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Folding of oligopyridine-dicarboxamides into helices inhibits the N-oxidation of pyridine rings central in the sequence and also much enhances the N-oxidation of pyridine rings peripheral in the sequence. Oligomers N-oxidized at their terminal position show an increased ability to hybridize into double helices. Copyright © 2005 American Chemical Society.

引用

页码：2400 / 2401

页数：2

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