Synthesis and application of planar-chiral phosphaferrocene-oxazolines, a new class of P,N-ligands

被引：88

作者：

Shintani, R ^{[1
]}

Lo, MMC ^{[1
]}

Fu, GC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 23期

关键词：

D O I：

10.1021/ol006606+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The synthesis of several phosphaferrocene-oxazolines, members of a new family of planar-chiral ligands, is described. These bidentate P,N-ligands are applied to enantioselective palladium-catalyzed allylic alkylations, for which it is shown that the planar-chirality of the phosphaferrocene, not the chirality of the oxazoline, determines the stereochemical outcome of the reaction.

引用

页码：3695 / 3697

页数：3

共 27 条

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