A novel 3D framework generated by unusual pillared 2D bilayer motifs

被引：34

作者：

Zhang, J

Li, ZJ

Cheng, JK

Kang, Y

Qin, YY

Yao, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 03期

关键词：

D O I：

10.1039/b415953e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydrothermally synthesized mixed-ligand molecular solid has been formulated. The X-ray diffraction analysis of a single crystal revealed a novel 3D architecture generated by unusual 2D bilayer motifs linked up by pillars. Three types of channels in one direction are established inside the structure.

引用

收藏

页码：421 / 423

页数：3

相关论文

共 23 条

[1] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[2] A novel 2D bilayer architecture generated via π-π interactions and host-guest molecular recognition:: assembly and structure of {[Cd(Htma)(bpy)(H2O)]•(H2tp)0.5•2H2O}n polymer (tma = trimesate, bpy = 4,4′-bipyridine, tp = terephthalate) [J].

Dai, JC ;

Hu, SM ;

Wu, XT ;

Fu, ZY ;

Du, WX ;

Zhang, HH ;

Sun, RQ .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (06) :914-918

[3] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures [J].

Dai, JC ;

Wu, XT ;

Fu, ZY ;

Cui, CP ;

Hu, SM ;

Du, WX ;

Wu, LM ;

Zhang, HH ;

Sun, RO .

INORGANIC CHEMISTRY, 2002, 41 (06) :1391-1396

[4] A design strategy for four-connected coordination frameworks [J].

Dolomanov, OV ;

Cordes, DB ;

Champness, NR ;

Blake, AJ ;

Hanton, LR ;

Jameson, GB ;

Schröder, M ;

Wilson, C .

CHEMICAL COMMUNICATIONS, 2004, (06) :642-643

[5] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[6]

FANG QR, 2004, J CHEM SOC DA, P2202

[7] A novel mixed-ligand molecular bilayer generated by self-assembly of "T-shaped" moieties, displaying an unusual entanglement [J].

Fu, ZY ;

Wu, XT ;

Dai, JC ;

Hu, SM ;

Du, WX .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (08) :978-980

[8] Interpenetration in [Cd(isonicotinate)2(1,2-bis(4-pyridyl)ethane)0.5(H2O)]n, a novel octahedral polymer containing an unusual two-dimensional bilayer motif generated by self-assembly of rectangle building blocks [J].

Fu, ZY ;

Wu, XT ;

Dai, JC ;

Wu, LM ;

Cui, CP ;

Hu, SM .

CHEMICAL COMMUNICATIONS, 2001, (18) :1856-1857

[9] From 1D chain to 3D network: Tuning hybrid II-VI nanostructures and their optical properties [J].

Huang, XY ;

Li, J ;

Zhang, Y ;

Mascarenhas, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (23) :7049-7055

[10] Zeolite-like crystal structure of an empty microporous molecular framework [J].

Kepert, CJ ;

Rosseinsky, MJ .

CHEMICAL COMMUNICATIONS, 1999, (04) :375-376