High yield synthesis and crystal structures of the Ru6-Sn cluster compounds [Ru6C(CO)16SnCl2] and [Ru6C(CO)16SnCl3]-

被引:69
作者
Hermans, S [1 ]
Johnson, BFG [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
关键词
D O I
10.1039/b004585n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Addition of two molar equivalents of SnCl4 to [Ru6C(CO)(16)](2-) yields first the new [Ru6C(CO)(16)SnCl3](-) cluster anion and then [Ru6C(CO)(16)SnCl2], the latter being also the single product of the direct addition of SnCl2 to [Ru6C(CO)(17)].
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页码:1955 / 1956
页数:2
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