A radical approach for the construction of the tricyclic core of stemoamide

被引：26

作者：

Bogliotti, N ^{[1
]}

Dalko, PI ^{[1
]}

Cossy, J ^{[1
]}

机构：

[1] ESPCI, CNRS, Lab Chim Organ Assoc, F-75231 Paris 05, France

来源：

SYNLETT | 2005年 / 02期

关键词：

radical cyclization; metathesis; stereoselective synthesis;

D O I：

10.1055/s-2004-837197

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rapid synthesis of (+/-)-9,10-bis-epi-stemoamide is presented. Three of the four contiguous stereocenters of this compound were set in a diastereoselective radical 7-exo-trig cyclization, which also allowed the construction of the tricyclic core of the molecule.

引用

页码：349 / 351

页数：3

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