Carbohydrate based formal synthesis of stemoamide using ring-closing metathesis

被引：46

作者：

Gurjar, MK ^{[1
]}

Reddy, DS ^{[1
]}

机构：

[1] Natl Chem Lab, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(01)02052-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthesis of stemoamide has been achieved from D-glucose. The stereocontrolled allylation under Barbier reaction conditions led to the installation of the 2-pyrrolidinone ring at C-3 followed by a ring-closing metathesis approach to construct the azepine ring system. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：295 / 298

页数：4

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