A new synthetic route to unsymmetrical bis(phthalocyaninato)europium(III) complexes

被引：51

作者：

Jiang, JZ ^{[1
]}

Liu, W

Law, WF

Lin, JM

Ng, DKP

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, New Territories, Peoples R China

[2] Shandong Univ, Dept Chem, Jinan 250100, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 1998年 / 268卷 / 01期

关键词：

phthalocyaninato complexes; europium complexes; heteroleptic complexes;

D O I：

10.1016/S0020-1693(97)05716-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of europium(III) acerylacetonate [Eu(acac)(3) . nH(2)O] with dilithium phthalocyaninate (Li2Pc) afforded Eu(acac) (Pc), which induced cyclic tetramerisation of 4,5-disubstituted phthalonitriles C6H2R2(CN)(2) (R=n-C7H15, OC5H11) producing the unsymmetrical bis(phthalocyaninato)europium(III) complexes Eu(Pc)[Pc*(R-8)] (Pc* = 2,3,9,10,16,17,23,24-octasubstituted phthalocyaninate) of which the spectroscopic and electrochemical properties were studied. (C) 1998 Elsevier Science S.A.

引用

页码：141 / 144

页数：4

共 20 条

[1] Phthalocyanines and associated compounds. Part XIV. Further investigations of metallic derivatives. [J].

Barrett, PA ;

Frye, DA ;

Linstead, RP .

JOURNAL OF THE CHEMICAL SOCIETY, 1938, :1157-1163

[2] SYNTHESIS AND ELECTRICAL-PROPERTIES OF A NEW MOLECULAR SEMICONDUCTOR - THE UNSYMMETRICAL LUTETIUM PHTHALONAPHTHALOCYANINE [J].

BASSOUL, P ;

SIMON, J .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 252 :31-38

[3] ELECTRICAL-PROPERTIES OF RARE-EARTH BISPHTHALOCYANINE AND BISNAPHTHALOCYANINE COMPLEXES [J].

BOUVET, M ;

SIMON, J .

CHEMICAL PHYSICS LETTERS, 1990, 172 (3-4) :299-302

[4] BIS(2,3-NAPHTHALOCYANINATO)LUTETIUM(III) AND (2,3-NAPHTHALOCYANINATO)(PHTHALOCYANINATO)LUTETIUM(III) COMPLEXES - SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND ELECTROCHEMISTRY [J].

GUYON, F ;

PONDAVEN, A ;

GUENOT, P ;

LHER, M .

INORGANIC CHEMISTRY, 1994, 33 (21) :4787-4793

[5] SYNTHESIS AND CHARACTERIZATION OF SOLUBLE PHTHALO-CYANINES - STRUCTURE-PROPERTY RELATIONSHIP [J].

HANACK, M ;

GUL, A ;

HIRSCH, A ;

MANDAL, BK ;

SUBRAMANIAN, LR ;

WITKE, E .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 187 :365-382

[6]

HANACK M, 1993, SYNTHESIS-STUTTGART, P387

[7] Synthesis and spectroscopic properties of heteroleptic sandwich-type (phthalocyaninato) (porphyrinato)lanthanide(III) complexes [J].

Jiang, JZ ;

Lau, RLC ;

Chan, TWD ;

Mak, TCW ;

Ng, DKP .

INORGANICA CHIMICA ACTA, 1997, 255 (01) :59-64

[8]

Jiang JZ, 1997, POLYHEDRON, V16, P515

[9] REDOX POTENTIALS OF A SERIES OF LANTHANIDE-BISPHTHALOCYANINE SANDWICH COMPLEXES [J].

KONAMI, H ;

HATANO, M ;

KOBAYASHI, N ;

OSA, T .

CHEMICAL PHYSICS LETTERS, 1990, 165 (05) :397-400

[10] Fourier transform ion cyclotron resonance studies of lanthanide(III) porphyrin-phthalocyanine heteroleptic sandwich complexes by using electrospray ionization [J].

Lau, RLC ;

Jiang, JZ ;

Ng, DKP ;

Chan, TWD .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1997, 8 (02) :161-169

← 1 2 →