Synthesis and characterization of tantalum silyl and disilyl imido complexes that do not contain anionic π-ligands

被引：22

作者：

Wu, ZZ ^{[1
]}

Xue, ZL ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 21期

关键词：

D O I：

10.1021/om000503d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tantalum disilyl and silyl complexes [(Me(3)Si)(2)N](Me(3)SiN=)Ta(SiPh(2)Bu(t))(2) (1) and [(Me(3)Si)(2)N](Me(2)N)(Me(3)SiN=)Ta(SiPh(2)Bu(t)) (2) have been prepared and characterized. They are; to our knowledge, the first known cyclopentadienyl-free group 5 imido disilyl and silyl complexes.

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页码：4191 / 4192

页数：2

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