Identification of supramolecular templates: design of solid-state photoreactivity using structural similarity

被引:79
作者
Shan, N [1 ]
Jones, W [1 ]
机构
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1016/S0040-4039(03)00685-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Structural similarity has been used to identify multifunctional templates for topochemically controlled solid-state photodimerisation. By examination of co-crystal structures of 4,4'-bipyridine with various acids, tricarballylic acid and 1,2,4,5-benzenetetracarboxylic acid have been identified as supramolecular templates for the alignment in the solid-state of 1,2-bis(4-pyridyl)ethylene. As a result, photodimerisation in the solid-state proceeds smoothly and with high yield. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3687 / 3689
页数:3
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