Identification of supramolecular templates: design of solid-state photoreactivity using structural similarity

被引：79

作者：

Shan, N ^{[1
]}

Jones, W ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(03)00685-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Structural similarity has been used to identify multifunctional templates for topochemically controlled solid-state photodimerisation. By examination of co-crystal structures of 4,4'-bipyridine with various acids, tricarballylic acid and 1,2,4,5-benzenetetracarboxylic acid have been identified as supramolecular templates for the alignment in the solid-state of 1,2-bis(4-pyridyl)ethylene. As a result, photodimerisation in the solid-state proceeds smoothly and with high yield. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3687 / 3689

页数：3

共 23 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[2]

Amirsakis DG, 2001, ANGEW CHEM INT EDIT, V40, P4256, DOI 10.1002/1521-3773(20011119)40:22<4256::AID-ANIE4256>3.0.CO

[3]

2-S

[4]

[Anonymous], 1997, SHELXS 97

[5] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].

BLESSING, RH .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38

[6]

*CCDC, 2002, CAMBR STRUCT DAT CON

[7] Phenyl-perfluorophenyl stacking interactions: Topochemical[2+2] photodimerization and photopolymerization of olefinic compounds [J].

Coates, GW ;

Dunn, AR ;

Henling, LM ;

Ziller, JW ;

Lobkovsky, EB ;

Grubbs, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (15) :3641-3649

[8] Discrete and infinite coordination arrays derived from a template-directed, solid-state, organic synthesis [J].

Hamilton, TD ;

Papaefstathiou, GS ;

MacGillivray, LR .

CRYSTENGCOMM, 2002, 4 :223-226

[9]

JONES W, 1997, ORGANIC MOL SOLIDS P, P164

[10] Hydrogen-bonding behaviour of benzene-1,2,4,5-tetracarboxylic acid:: supramolecular structures of different dimensionality in the 2:1 adducts formed with 4,4′-bipyridyl and hexamethylenetetramine [J].

Lough, AJ ;

Wheatley, PS ;

Ferguson, G ;

Glidewell, C .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2000, 56 (02) :261-272

← 1 2 3 →