Triphenylphosphine chalcogenides as efficient ligands for room temperature palladium(II)-catalyzed Suzuki-Miyaura reaction

被引：57

作者：

Das, Pankaj ^{[1
]}

Bora, Utpal ^{[1
]}

Tairai, Archana ^{[1
]}

Sharma, Chandan ^{[1
]}

机构：

[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 11期

关键词：

Suzuki-Miyaura reaction; Palladium chloride; Triphenylphosphine chalcogenides; CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYST; ARYL CHLORIDES; PHOSPHINE OXIDES; COMPLEXES; PALLADIUM(0); PD/C; AMINATION; HALIDES; SYSTEM;

D O I：

10.1016/j.tetlet.2010.01.032

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学];

摘要：

A simple catalytic system based on PdCl2 and triphenylphosphine chalcogenides (PPh3X; X = O, S, Se) is found to be highly effective (up to 97% isolated yield) in the room temperature Suzuki-Miyaura reactions. Under the same experimental conditions, triphenylphosphine chalcogenides as ligands show superior activities compared to free triphenylphosphine. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1479 / 1482

页数：4

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