In situ studies of metal passive films

被引：42

作者：

Diez-Perez, Ismael

Sanz, Fausto

Gorostiza, Pau

机构：

[1] Univ Barcelona, Inst Bioengn Catalunya, IBEC, E-08028 Barcelona, Spain

[2] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 2006年 / 10卷 / 3-4期

关键词：

voltammetry; EIS; SERS; XRD; XANES; electrochemical STM; electrochemical tunneling spectroscopy; ECTS; oxide; iron; copper; nickel; tin; passivity; semiconductor electrochemistry; chloride corrosion;

D O I：

10.1016/j.cossms.2007.01.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The understanding of metal passivation has greatly improved in the recent years due to the development of in situ experimental techniques. It is now possible to characterize at the nanoscale the chemical composition, structure and electronic properties of oxide films that grow on the surface of metals, while keeping them in solution and under potentiostatic control. This knowledge is allowing to elucidate the mechanisms of metal passivation and is providing great advances in the characterization of other dynamic, complex processes like passivity breakdown induced by chloride. (c) 2007 Elsevier Ltd. All rights reserved.

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页码：144 / 152

页数：9

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