Staircase-form assembly with 5,15-bis(imidazol-4-yl)porphinatogallium steps

被引：16

作者：

Nagata, N ^{[1
]}

Kugimiya, S ^{[1
]}

Fujiwara, E ^{[1
]}

Kobuke, Y ^{[1
]}

机构：

[1] JST, Grad Sch Mat Sci, Nara Inst Sci & Technol, CREST, Ikoma 6300101, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 04期

关键词：

D O I：

10.1039/b211839d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large supramolecular assemblies of 5,15-bis(imidazol-4-yl)porphinatogallium 2Ga have been synthesized by hexacoordination of two imidazolyl groups to Ga(III) in a staircase arrangement of porphyrin planes as each "step''. The structure of the supramolecular assembly was characterized by UV, X-ray diffraction, and AFM. The conductivity of 2Ga films was enhanced 8 times by photoirradiation.

引用

页码：743 / 747

页数：5

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