One-pot electrochemical formation of meso,meso-linked porphyrin arrays

被引:88
作者
Ogawa, T [1 ]
Nishimoto, Y
Yoshida, N
Ono, N
Osukua, A
机构
[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan
[2] Ehime Univ, Fac Sci, Dept Chem, Matsuyama, Ehime 790, Japan
[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 60601, Japan
关键词
D O I
10.1039/a707653c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochemical oxidation of [5,15-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 1, [5,15-bis(4-methoxycarbonylphenyl)porphyrinato]zinc(II), [5,15-bis(pentafluorophenyl)porphyrinato] zinc(II), or [10-bromo-5,15-diphenylporphyrinato]zinc(II) in benzonitrile using a platinum net as the working electrode afforded the corresponding meso,meso-linked oligomer porphyrin arrays, and up to the octamer porphyrin array could be isolated for 1.
引用
收藏
页码:337 / 338
页数:2
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