Heavy allenes and cumulenes E=C=E′ and E=C=C=E′ (E = P, As, Si, Ge, Sn;: E′ = C, N, P, As, O, S)

被引：126

作者：

Escudié, J ^{[1
]}

Ranaivonjatovo, H ^{[1
]}

Rigon, L ^{[1
]}

机构：

[1] Univ Toulouse 3, UMR 5069, F-31062 Toulouse 04, France

来源：

CHEMICAL REVIEWS | 2000年 / 100卷 / 10期

关键词：

D O I：

10.1021/cr990013z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transient or stable compounds of heavy allenes and cumulenes with general formulas E double bond C double bond E′ and E double bond C double bond C double bond E′ were synthesized. The allenic phosphorus compounds studied include: 1-phosphaallenes; 1,3-phosphaazaallenes; 1,3-diphosphaallenes; 1,3-arsaphosphaallenes; phosphaketenes; and phosphathioketenes. The physicochemical and chemical behaviors of the compounds revealed several peculiarities.

引用

页码：3639 / 3696

页数：58

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