Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes

被引:1535
作者
Cordes, David B. [1 ]
Lickiss, Paul D. [1 ]
Rataboul, Franck [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
关键词
OLIGOMERIC SILSESQUIOXANE POSS; ORGANIC-INORGANIC HYBRID; LIGHT-EMITTING-DIODES; POLY(METHYL METHACRYLATE) NANOCOMPOSITES; SOLUTION PROCESSABLE NANOCOMPOSITES; TRANSFER RADICAL POLYMERIZATION; MOLECULAR-DYNAMICS SIMULATIONS; MOBILITY MASS-SPECTROMETRY; METAL FUNCTIONALIZED POSS; RAY CRYSTAL-STRUCTURE;
D O I
10.1021/cr900201r
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Some of the latest developments in the investigations of the chemistry of cubic polyhedral oligosilsesquioxanes were reviewed. The review focued on investigating the chemistry of those compounds that were based on the (RSiO 3/2)8 formula. The general structure of RSiO 3/2)8 revealed some of the significant features of these molecules, including the siloxane cage size and the distribution of the eight pendant arms from the cube in a three-dimensional arrangement. The review also focused on on the synthesis, properties, and applications of molecular T 8R8 compounds in place of their properties and applications within polymeric materials. The findings of the review focused on the synthesis of T8 POSS, which were earlier unknown species and new syntheses of known species.
引用
收藏
页码:2081 / 2173
页数:93
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