An unexpected redistribution of trichlorosilane.: Synthesis, structure and bonding of (N,N,N′,N′-tetraethylethylenediamine)dichlorosilane

被引：32

作者：

Boudjouk, P ^{[1
]}

Kloos, SD ^{[1
]}

Kim, BK ^{[1
]}

Page, M ^{[1
]}

Thweatt, D ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem, Ctr Main Grp Chem, Fargo, ND 58105 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a800240a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N,N,N',N'-Tetraethylethylenediamine (teeda) redistributes trichlorosilane to form the novel six-co-ordinate complex, (teeda)SiH2Cl2 and tetrachlorosilane.

引用

页码：877 / 879

页数：3

共 31 条

[1] EXCLUSIVE BETA-HYDROSILYLATION OF ACRYLATES CATALYZED BY COPPER-TETRAMETHYLETHYLENEDIAMINE [J].

BOUDJOUK, P ;

KLOOS, S ;

RAJKUMAR, AB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 443 (02) :C41-C43

[2] The electron diffraction investigation of the molecular structures of (1) Phosphorus oxytrichloride, oxydichlorofluoride, oxychlorodifluoride, oxytrifluoride, fluorodichloride, pentafluoride, and trifluorodichloride, and of (2) Disilane, trichlorosilane, and hexachlorodisilane [J].

Brockway, LO ;

Beach, JY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :1836-1846

[3] An investigation of the chlorosilanes and of chloro- and bromo-acetylene by electron diffraction and electric dipole moment measurements on the vapours. [J].

Brockway, LO ;

Coop, IE .

TRANSACTIONS OF THE FARADAY SOCIETY, 1938, 34 (02) :1429-1438

[4] TRIMETHYLAMINE ADDUCTS OF THE CHLOROSILANES [J].

BURG, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (10) :2674-2675

[5] ADDUCTS OF HALOGENOSILANES .2. PHYSICAL PROPERTIES AND STRUCTURES [J].

CAMPBELL.HJ ;

EBSWORTH, EA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (05) :705-&

[6]

CAMPBELLFERGUSO.HJ, 1996, J CHEM SOC A, P1508

[7] INTRAMOLECULAR BASE STABILIZATION OF SILICENIUM IONS - A NEW ROUTE TO SILICONIUM IONS [J].

CHUIT, C ;

CORRIU, RJP ;

MEHDI, A ;

REYE, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09) :1311-1313

[8] REACTIVITY OF PENTACOORDINATE AND HEXACOORDINATE SILICON-COMPOUNDS AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CHUIT, C ;

CORRIU, RJP ;

REYE, C ;

YOUNG, JC .

CHEMICAL REVIEWS, 1993, 93 (04) :1371-1448

[9] PENTACOORDINATED SILICON-COMPOUNDS - INTRAMOLECULAR RING-CLOSURE, SITE PREFERENCES OF SUBSTITUENTS AND THE STABILITY OF THE RESULTING CHELATES [J].

CORRIU, RJP ;

KPOTON, A ;

POIRIER, M ;

ROYO, G ;

DESAXCE, A ;

YOUNG, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (01) :1-26

[10]

Davy J, 1812, PHIL T, V102, P352

← 1 2 3 4 →