INTRAMOLECULAR BASE STABILIZATION OF SILICENIUM IONS - A NEW ROUTE TO SILICONIUM IONS

被引：63

作者：

CHUIT, C

CORRIU, RJP

MEHDI, A

REYE, C

机构：

[1] Université de Montpellier II, Sciences et Techniques du Languedoc, URA, Montpellier, F-34095, Place Eugène Bataillon

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silicon atom is pentacoordinate in cations of salts like 1, which can be prepared, for instance, in a redox reaction of the corresponding silane (with I2, X = I) or transformation with electrophiles like PhCoCl (X = Cl) or Ph3C+BF 4− (X= BF4). These compounds were completely characterized; conductivity titrations confirm that they are ionic. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1311 / 1313

页数：3

共 34 条

[1] FORMATION AND REACTIVITY OF SILICON SULFUR AND SILICON SELENIUM DOUBLE-BONDS - THE 1ST X-RAY STRUCTURE OF A SILANETHIONE [J].

ARYA, P ;

BOYER, J ;

CARRE, F ;

CORRIU, R ;

LANNEAU, G ;

LAPASSET, J ;

PERROT, M ;

PRIOU, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (08) :1016-1018

[2]

ARYA P, 1989, ANGEW CHEM, V101, P1069

[3] THE PREPARATION AND OBSERVATION BY SI-29 NMR-SPECTROSCOPY OF SIMPLE, ACYCLIC, 5-CO-ORDINATE SILICON SALTS [J].

BASSINDALE, AR ;

STOUT, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (21) :1387-1389

[4] 5-CO-ORDINATED SILICON-COMPOUNDS - GEOMETRY OF FORMATION BY INTRAMOLECULAR COORDINATION - CRYSTAL-STRUCTURE OF 2-(DIMETHYLAMINOMETHYL)PHENYL-1-NAPHTHYLSILANE [J].

BOYER, J ;

BRELIERE, C ;

CARRE, F ;

CORRIU, RJP ;

KPOTON, A ;

POIRIER, M ;

ROYO, G ;

YOUNG, JC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (01) :43-51

[5] ADDUCTS OF HALOGENOSILANES .2. PHYSICAL PROPERTIES AND STRUCTURES [J].

CAMPBELL.HJ ;

EBSWORTH, EA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (05) :705-&

[6] REACTIVITY OF PENTACOORDINATE AND HEXACOORDINATE SILICON-COMPOUNDS AND THEIR ROLE AS REACTION INTERMEDIATES [J].

CHUIT, C ;

CORRIU, RJP ;

REYE, C ;

YOUNG, JC .

CHEMICAL REVIEWS, 1993, 93 (04) :1371-1448

[7] TRIPHENYL (BIPYRIDYL) SILICONIUM ION [J].

COREY, JY ;

WEST, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (24) :4034-&

[8] INTRAMOLECULAR BASE STABILIZATION OF SI=N AND SI=P COMPOUNDS AND RELATED TRANSITION-METAL SILANEDIYL COMPLEXES [J].

CORRIU, R ;

LANNEAU, G ;

PRIOU, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (09) :1130-1132

[9]

Corriu R., 1991, ANGEW CHEM, V103, P1153

[10] SILICONIUM ION QUESTION [J].

CORRIU, RJP ;

HENNER, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 74 (01) :1-28

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