Quantum Dot-Dye Bilayer-Sensitized Solar Cells: Breaking the Limits Imposed by the Low Absorbance of Dye Monolayers

被引:133
作者
Shalom, Menny
Albero, Josep
Tachan, Zion
Martinez-Ferrero, Eugenia
Zaban, Arie [1 ]
Palomares, Emilio
机构
[1] Bar Ilan Univ, Dept Chem, Inst Nanotechnol & Adv Mat, IL-52900 Ramat Gan, Israel
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2010年 / 1卷 / 07期
基金
欧洲研究理事会; 以色列科学基金会;
关键词
SIZE; RECOMBINATION; NANOCRYSTALS; DEPOSITION; FILMS; CDSE;
D O I
10.1021/jz1002555
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Here, we present a new DSSC design, consisting of sequential QDs and dye sensitization layers, that opens the path toward high optical density DSSCs that cover a significant part of the solar spectrum. The new configuration is enabled by the application of an amorphous TiO2 layer between the two sensitizers, allowing both electron injection from the outer absorber and fast hole extraction from the inner sensitizing layer. Utilizing two sensitizing layers, we obtain a 250% increase in cell efficiency compared to a QD monolayer cell.
引用
收藏
页码:1134 / 1138
页数:5
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