Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

被引:6
作者
Chen KeFan [1 ]
Deng JianHua [1 ]
Zhao Fei [1 ]
Cheng GuoAn [1 ]
Zheng RuiTing [1 ]
机构
[1] Beijing Normal Univ, Coll Nucl Sci & Technol, Minist Educ, Key Lab Beam Technol & Mat Modificat, Beijing 100875, Peoples R China
基金
中国国家自然科学基金;
关键词
multi-walled carbon nanotubes; ion implantation; field electron emission; BORON; DEPOSITION; FILMS;
D O I
10.1007/s11431-009-0384-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated. The results revealed that Zn+ implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure. Meanwhile, C: Zn solid solution was synthesized after Zn+ implantation. The turn-on field and threshold field were 0.80 and 1.31 V/mu m, respectively for original multi-walled carbon nanotube arrays and were reduced to 0.66 and 1.04 V/mu m due to the synthesis of C and Zn composite, in which the work function was reduced after low doses of Zn+ implantation. It is indicated that low doses of Zn+ implantation can improve field emission performance of multi-walled carbon nanotube arrays. Otherwise, high doses of Zn+ implantation can reduce field emission properties of multi-walled carbon nanotube arrays, because radiation damage reduces the electric field enhancement factor.
引用
收藏
页码:776 / 781
页数:6
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